000 01662nam a22002057a 4500
100 _aWang, X
245 _aIntroducing tea polyphenols and vitamin c to improve the in situ hydrogenation and reduction process of NBR and NBR/GO latex
260 _bRubber Chemistry and Technology, 95(3): 450-464.
_c2022
300 _bJuly-September
520 _aTea polyphenols and vitamin C are used as reducing agents that are introduced into nitrile–butadiene rubber (NBR) and NBR/graphene oxide (GO) latex systems, and the double bonds in the NBR and the GO sheet in NBR/GO are simultaneously hydrogenated and reduced through the synergistic hydrazine hydrate/hydrogen peroxide/copper sulfate catalytic system to prepare hydrogenated NBR (HNBR) and HNBR/reduced GO (RGO) nanocomposites. The degree of hydrogenation of the product is improved and the gel content of the product is reduced, which effectively solves the problems of the low degree of hydrogenation and high gel content in the diimide catalytic hydrogenation system. At the same time, the HNBR and HNBR/RGO nanocomposites, which are co-reduced by tea polyphenols and vitamin C, have good thermal stability and mechanical properties. Tea polyphenols are more likely to participate in the hydrogenation reaction. The degree of hydrogenation of the NBR double bonds is higher than the amount of reduction occurring within the GO sheet with the addition of tea polyphenols.
650 _aTea polyphenols
650 _aVitamin C
650 _aNGO/GO
700 _aPan, H
700 _aCao, L
700 _aWang, C
700 _aZong, C
856 _uhttps://doi.org/10.5254/rct.22.77994
942 _cJS
999 _c74959
_d74959