000 01527nam a2200205Ia 4500
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100 _aSakdapipanich Jitladda Tangpakdee
245 0 _aStructural characterisation of the small rubber particles in fresh Hevea latex
260 _bJournal of Rubber Research
_c1999
300 _a160-168
520 _aThe rubbers from small and large rubber particles were separated from the serum and cream phases of centrifuged fresh Hevea latex, respectively. The small rubber particles (SRP) consist of rubber molecules showing a unimodel molecular weight distribution (MWD) with a peak-top value falling between the two peak values of the bimodal MWD observed in rubbers from the large rubber particles (LRP). The rubber in LRP from mature trees and SRP from seedlings are polyisoprene molecules terminated by phospholipids comprising branching points, while that in SRP are presumed to be linear molecules containing no phospholipid terminal. Comparative data of MW and structure between the SRP obtained from the serum phase of fresh latex and those of the SRP obtained from seedling latex are reported. The mechanism controlling MW in connection with the relationship among MW, branching, gel and particle size.
650 _aHevea latex
650 _aMolecular weight distribution
650 _aSmall rubber particles
650 _aStructural analysis
650 _aStructural characterisation
700 _aSuksujaritporn Sirisak
700 _aTanaka Yasuyuki
942 _cJS
999 _c69438
_d69438