000 01095nam a2200157Ia 4500
008 220216s9999 xx 000 0 und d
100 _aEng A H
245 0 _aReaction of moist ozone with natural rubber: A study by attenuatedtotal reflectance spectroscopy
260 _bJournal of Rubber Research
_c1998
300 _a133-145
520 _aSurface treatment of prevulcanised latex film with ozone water leads to the formation of ester, aldehyde, and ketone groups as indicated by a FTIR-ATR study. In the presence of proteins, the carbonyl oxide zwitterion intermediate reacts with the amino groups of the protein to produce rubber-bonded proteins on the surface. In the case of ozone-treated wet rubber gel, the tensile strength of the film remains high, indicating no significant ozone penetration. The reaction of ozone with natural rubber in the wet gel state may be used ot chemically modify the surface of natural rubber products without sacrificing the excellent physical properties of the rubber.
700 _aKawasaki H
700 _aKodama S
700 _aNagata K
942 _cJS
999 _c66363
_d66363