000 02386nam a2200217Ia 4500
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100 _aWang Y Z
245 0 _aInfluences of coagulam maturation time of rubber latex coagulated with formic acid and microorganism on the effective storage time of natural rubber
260 _bJournal of Rubber Research
_c2014
300 _a233-244
500 _aSource Year: 2014
520 _aFresh NR latex was coagulated using formic acid and microorganism. The resulting coagula were matured at various conditions, followed by creping, size reduction and drying at 115 degree C for 5 hours. The dried coagula were then scanned using differential scanning calorimetry (DSC) and aged at various ageing times at 70 degree C. The effective storage time (i.e. storage life) of the coagula was evaluated through heat accelerated storage ageing combined with the Doyle-Ozawa equation and the heat ageing life equation. The results showed that the effective storage time of natural rubber prepared by the coagulum of fresh latex coagulated with formic acid and matured for 6, 12, 18 and 24 h respectively increased to 45.6 years from 23.2 years at 30 degree C, and increased to 100.5 years from 46.7 years at 25 degree C. The effective storage time of natural rubber prepared by the coagulum of fresh latex coagulated with microorganisms and matured for 6, 12, 18 and 24 h respectively increased to 83.3 years from 57.7 years at 30 degree C, and increased to 206.3 years from 132.8 years at 25 degree C. Both effective storage time of natural rubbers coagulated with formic acid and microorganism increased with the prolonging of coagulum maturation time. The effective storage time of NR from the coagulum matured for 6-12 h increased fast, the effective storage time of NR prepared by the coagulum matured for 12-18 h increase slowly and the increase in the effective storage time of NR prepared by the coagulum matured for 18-24 h tend to be flat. The effective storage time of natural rubber coagulated with microorganisms is obviously longer than that of natural rubber coagulated with formic acid in the same storage conditions.
650 _aAgeing
650 _aCoagulum maturation
650 _aEffective storage time
650 _aFresh latex
650 _aNatural Rubber
700 _aHuang H H
700 _aZhang B L
942 _cJS
999 _c61376
_d61376