000 01362nam a2200169Ia 4500
008 220216s9999 xx 000 0 und d
100 _aFurukawa M
245 0 _aFunctionally graded polyurethane elastomers prepared by electrophoresis of monomer
260 _bJournal of Natural Rubber Research
_c1997
300 _a237-246
520 _aA novel preparation method of functionally graded interpenetrating network polymer(IPN)-type elastomers, was proposed. Functionally graded IPN-type polyurethane elastomers (PUEs) were prepared by electrophoresis of ionic monomers. The base PUEs were prepared from poly(oxytetramethylene) glycol (PTMG) and/or poly(oxyethylene) glycol (PEG), 4,4-diphenylmethane diisocynate (MDI), and a mixture of 1,4-butane diol with trimethylol propane (TMP). Ionic monomers used were methacrylic acid and quarternary N,N-dimethylamino ethyl acrylate. Effects of the electrophoresis time of monomer on morphologies and mechanical properties were studied by DSC, polarising microscopy, etc. Spherulite sizes of the modified PUEs depended significantly on the electrophoresis time. Abrasion resistance of the surface of IPN-type PUEs evaluated by DIN abrasion test was better than that of non-treated PUE.
650 _aElectrophoresis
650 _aPolyurethane elastomers
700 _aOkazaki T
700 _aShiiba T
942 _cJS
999 _c59635
_d59635