000 01333nam a2200157Ia 4500
008 220216s9999 xx 000 0 und d
100 _aClaramma N M
245 0 _aEffect of temperature on sulfur prevulcanization of natural rubber latex
260 _bJournal of Applied Polymer Science
_c1997
300 _a1913-1920
520 _aSulfur prevulcanization of natural rubber latex was conducted at 60, 70, 80, and 90 C for different periods. The extent of crosslinking was assessed. Tensile properties, water absorption, leaching, and stress-relaxation characteristics of the films were also evaluated. The volume fraction of rubber (Vr), which is a measure of crosslink density of the films, showeed a maximum when prevulcanization was conducted at 80 C for 2h or at 90 C for 1h. At lower temperatures, the rate of reaction was slow. At each temperature, tensile strength and elongation at break decreased when the prevulcanization time increased, whereas the modulus increased up to a maximum crosslinking and thereafter decreased. Water absorption and leaching were more rapid in prevulcanized film than in postvulcanized film. The rate of stress relaxation slightly increased as the extent of prevulcanization increased.
650 _aNatural rubber latex
650 _aPrevulcanization
700 _aMathew N M
942 _cJS
999 _c58193
_d58193