000			01442nam a2200217Ia 4500
008			220216s9999 xx 000 0 und d
100			_aManna Ajay K
245		0	_aEffect of surface oxidation of carbon black on its bonding with epoxidized natural rubber in the presence of silane coupling agent
260			_bRubber Chemistry and Technology _c1999
300			_a398-409
520			_aResults of bound rubber determination, Monsanto rheometry, solvent swelling studies and measurement of physical properties reveal that high temperature molding of epoxidized natural rubber (ENR) filled with intermediate super abrasion furnace(ISAF) carbon black and surface oxidized ISAF carbon black, in the presence of silane coupling agent, namely, N-(4-vinylbenzyl)-N-[3-(trimethoxysily)propyl]ethane-1,2-diamine monoHCI salt, results in crosslinking of the rubber phase, even in the absence of the vulcanizing agents. Infrared spectroscopic studies show formation of silyl ether, in the case of ISAF carbon black, whereas the oxidized grade forms both silyl ether as well as silyl ester and amide linkage. Oxidation of ISAF carbon black causes an increase in the extent of coupling bond formation.
650			_aBonding
650			_aCarbon black
650			_aEpoxidized natural rubber
650			_aSilane coupling agent
650			_aSurface oxidation
700			_aDe P P
700			_aDe S K
700			_aTripathy D K
942			_cJS
999			_c58181 _d58181