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100 _aIbrahim S
245 0 _aChemical degradation of natural rubber latex in acidic medium catalysed by CoCl2 and (NH4)2 Fe(SO4)2
260 _bJournal of Rubber Research
_c2015
300 _a61-71
500 _aSource Year: 2015
520 _aLiquid natural rubber (LNR) is a derivative of natural rubber (NR) which has a molecular weight of less than 50,000 g/mol. In this study, LNR was prepared via chemical degradation reaction using hydrogen peroxide and sodium nitrite as reagents in latex solution. Compared to the reaction without catalyst, molecular weight of LNR obtained was found to decrease approximately three and two times in the presence of cobalt chloride (CoCl2) and ferrous ammonium sulphate ((NH4)2Fe(SO4)2), respectively. Using the method described, the degradation reaction generates functional groups such as hydroxyl and carbonyl in the LNR chains. In the presence of these catalyst, the hydroxyl groups are decreased and contrarily carbonyl groups in the LNR chains are increased.
650 _aCobalt chloride
650 _aFerrous ammonium sulphate
650 _aLiquid natural rubber(LNR)
650 _aRedox reaction
700 _aMustafa A
700 _aTan K S
942 _cJS
999 _c55493
_d55493