000			02050nam a2200181Ia 4500
008			220104s9999 xx 000 0 und d
100			_aOkieimen F E
245		0	_aStudies in molecular weight determination of rubber seed oil alkyds
520			_aMolecular weights of six samples of rubber seed oil alkyds having oil content of 20;(I), 30;(II), 35;(III), 40;(IV), 50;(V), and 60;(VI) prepared with phthalic anhydride, glycerol and rubber seed oil were determined (Rast methos) and calculated (endgroup analysis). Properties of the rubber seed oil were specific gravity 0.926, colour 0.5R 10Y, free fatty acid 11.29, peroxide value 0.40, saponification value 192.93, iodine value 155.56 and unsaponifiable matter (;)0.84. Average molecular weights determined, ranged from 441.11 for sample III to 1323.33 for sample V and those calculated were found to be larger than the values determined. Rast method seems to be a more reasonable method of average molecular weight determination for routine analysis. The differences observed were attributed to the assumption that only interesterification reactions occur during alkyd preparation in calculating average molecular weights. Fractionation of the alkyds showed that rubber seed oilalkyds consist of fractions of varying molecularweights. Study of molecular weight distribution showed that species of low average molecular weight constitute greater proportion of the alkyds. Average molecular weihts of the final alkyds to air-dry was found to be dependent on solid content, viscocity of alkyd solution and level of unsaturation in the final alkyd. Thus alkyds containing 40;rubber seed oil and above were found to be air-drying while those containing lower oil content are considered suitable in formulating baked finishes or can be combined with other film-forming resins.
650			_a _Drying time
650			_aAlkyd resins
650			_aAverage molecular weight
650			_aPolymerization
650			_aRubber seed oil
650			_aViscosity
700			_aAigbodion A I
942			_cBE
999			_c47350 _d47350