Effect of addition of polyethylene on properties of polypropylene/ethylene-propylene rubber blends
Material type:
TextPublication details: Journal of Applied Polymer Science 1996Description: 301-310Subject(s): Summary: Toughening of polypropylene was carried out by adding two types of ethylene-propylene rubber (EPR) having different ethylene content, and three commercial types or EPR containing high density polyethylene (PE). The concentration of EPR was varied from 0-30;. Globular morphology of the dispersed phase was observed at all concentrations. Average particle size of the dispersed phase (EPR) was about 2-4 mm with about 10;within the 0.5-1mm range. Although most of the properties were not affected by the presence of polyethylene, high notched Izod impact strength was achieved only with samples containing PE. Melt flow rate, yield strength and modulus were found to decrease almost linearly with increasing elastomer concentration in the blend. Elongation at break was enhanced by the addition of EPR, particularly those containing PE. The contribution of PE to the properties was explained by the specific EPR/PE particle morphology (core-shell or interpenetrating) but the exact mechanism of toughening of PP with EPR in the presence of PE is not clear.
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RRII Library Rubber chemistry | Volume 59, Issue 2 | Journals |
Toughening of polypropylene was carried out by adding two types of ethylene-propylene rubber (EPR) having different ethylene content, and three commercial types or EPR containing high density polyethylene (PE). The concentration of EPR was varied from 0-30;. Globular morphology of the dispersed phase was observed at all concentrations. Average particle size of the dispersed phase (EPR) was about 2-4 mm with about 10;within the 0.5-1mm range. Although most of the properties were not affected by the presence of polyethylene, high notched Izod impact strength was achieved only with samples containing PE. Melt flow rate, yield strength and modulus were found to decrease almost linearly with increasing elastomer concentration in the blend. Elongation at break was enhanced by the addition of EPR, particularly those containing PE. The contribution of PE to the properties was explained by the specific EPR/PE particle morphology (core-shell or interpenetrating) but the exact mechanism of toughening of PP with EPR in the presence of PE is not clear.
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