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Morphology, physical and flame retardant properties of epoxidised natural rubber (ENR) organoclay compound

By: Contributor(s): Material type: TextTextPublication details: Journal of Rubber Research 2013Description: 91-100Subject(s): Summary: Epoxidised natural rubber (ENR) has good oil resistance and gas barrier properties. Despite a number of superior qualities, one of the drawbacks that limits usage of ENR is its inherent high flammability. Currently, much attention is focused on the use of layered silicates (clay), to produce materials with enhanced flame retardance and superior physical properties. Therefore. Therefore, in this study, we investigate the effect of nanoclay on the flame behaviour and physical properties of ENR 50. Several tests including limiting oxygen index (LOI), underwriters laboratory (UL-94), tensile strength and morphology characterisation were performed on ENR 50 filled with 10 p.p.h.r. for all types of claytested could not self extinguish. According to the vertical burning test, UL-94, there is no classification or rating given to such materials.Similarly, the incorporation of clay in ENR did not enhance the LOI value. The improvement in physical and barrier properties of ENR containing C 15 A indicated that an exfoliated structure was formed in the rubber matrix as supported by X-ray diffraction (XRD) and transmission electron microscopy (TEM) results.
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Journals Journals RRII Library Rubber technology Volume 16, Issue 2 Journals
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Epoxidised natural rubber (ENR) has good oil resistance and gas barrier properties. Despite a number of superior qualities, one of the drawbacks that limits usage of ENR is its inherent high flammability. Currently, much attention is focused on the use of layered silicates (clay), to produce materials with enhanced flame retardance and superior physical properties. Therefore. Therefore, in this study, we investigate the effect of nanoclay on the flame behaviour and physical properties of ENR 50. Several tests including limiting oxygen index (LOI), underwriters laboratory (UL-94), tensile strength and morphology characterisation were performed on ENR 50 filled with 10 p.p.h.r. for all types of claytested could not self extinguish. According to the vertical burning test, UL-94, there is no classification or rating given to such materials.Similarly, the incorporation of clay in ENR did not enhance the LOI value. The improvement in physical and barrier properties of ENR containing C 15 A indicated that an exfoliated structure was formed in the rubber matrix as supported by X-ray diffraction (XRD) and transmission electron microscopy (TEM) results.

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