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Rheological studies of dynamically vulcanized and mechanical blends of polypropylene and ethylene-Propylene rubber

By: Contributor(s): Material type: TextTextPublication details: Rubber Chemistry and Technology 1995Description: 728-738Subject(s): Summary: An experimental study is presented of the rheological properties of (i) polypropylene, (ii) a mechanical blend of a polypropylene and an ethylene-propylene copolymer. The polypropylene behaves as a typical flexible chain thermoplastic exhibiting a zero shear viscosity and higher rate non-Newtonian viscosity, well defined normal stresses, an elongational viscosity three times the zeroshear viscosity, and an equality of the shear viscosity and the complex viscosity (Cox-Merz Rule). The PP/EPDM-TPE exhibits an apparent yield value in shear flow, unmeasurable normal stresses and a complex viscosity which is much greater than the shear viscosity. This is behavior similar to that of particle filled compounds, block copolymers and liquid crystalline thermoplastics and suggests a material with a rest state structure. The behavior of the PP/EPM mechanical blend is intermediate.
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Item type Current library Vol info Status
Journals Journals RRII Library Rubber chemistry Volume 68, Issue 5 Journals
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An experimental study is presented of the rheological properties of (i) polypropylene, (ii) a mechanical blend of a polypropylene and an ethylene-propylene copolymer. The polypropylene behaves as a typical flexible chain thermoplastic exhibiting a zero shear viscosity and higher rate non-Newtonian viscosity, well defined normal stresses, an elongational viscosity three times the zeroshear viscosity, and an equality of the shear viscosity and the complex viscosity (Cox-Merz Rule). The PP/EPDM-TPE exhibits an apparent yield value in shear flow, unmeasurable normal stresses and a complex viscosity which is much greater than the shear viscosity. This is behavior similar to that of particle filled compounds, block copolymers and liquid crystalline thermoplastics and suggests a material with a rest state structure. The behavior of the PP/EPM mechanical blend is intermediate.

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