TY - BOOK AU - Aigbodion A I AU - Pillai C K TI - Synthesis and molecular weight characterisation of rubber seed oil-modified alkyd resins PY - 2001/// PB - Journal of Applied Polymer Science KW - Alkyd resins KW - Molecular weight KW - Rubber seed KW - Rubber seed oil N1 - Source Year: 2001 N2 - Alkyd resins of 40;, 50;and 60;oil length (OL) are prepared with rubber seed oil (RSO), phthalic anhydride (PA) and glycerol (GLY), employing the two-stage alcoholysis method. Changes in the , physical characteristics of the reaction medium are monitored by determination of the acid value and the number-average molecular weight, Mn, of in-process samples withdrawn at different stages of the reaction. The mode of variation of these properties denotes that the preparation of RSO alkyds is complex. Molecular weight averages and the molecular weight distribution (MWD) of the finished alkyds are determined by GPC, cryoscopy and end-group analysis. Molecular weight averages and the MWD vary with differences in the formulation, with sample II exhibiting the narrowest size distribution UR - RAPRA ER -