TY  - BOOK
AU  - Mosch A
AU  - Giese U
AU  - Schuster R H
TI  - Investigation of the accelerated sulfur vulcanization of polydienes 1 - Reaction products of vulcanization of NR with CBS/S
PY  - 2003///
PB  - Kautschuk Gummi Kunststoffe
KW  - LC-MS-analysis
KW  - Sulfur vulcanization
KW  - Time concentration relationships of reaction products
N2  - The curing process of NR with different CBS/S- ratios was studied in order to get more information about the mechanism of the accelerated sulfur vulcanization. Time dependent collected extracts of the vulcanizates were analyzed by means of HPLC-MS and HPLC-UV. The MS-analysis shows the existence of dibenzothiazolyl-polysulfides during the scorch period. Quantitative analysis of the soluble reaction products demonstrates the influence of the sulfur-accelerator-ratio to the dispoportion of the accelerator and the rate of the crosslinking reaction
ER  -