CHARACTERIZATION OF 2-THIOBENZOTHIAZOLE/ P-PHENYLENEDIAMINE VULCANIZATION INTERMEDIATE AND ITS INFLUENCE ON VULCANIZATION (Record no. 75308)
[ view plain ]
| 000 -LEADER | |
|---|---|
| fixed length control field | 01497nam a22001817a 4500 |
| 100 ## - MAIN ENTRY--AUTHOR NAME | |
| Personal name | Wen, S. |
| 245 ## - TITLE STATEMENT | |
| Title | CHARACTERIZATION OF 2-THIOBENZOTHIAZOLE/ P-PHENYLENEDIAMINE VULCANIZATION INTERMEDIATE AND ITS INFLUENCE ON VULCANIZATION |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
| Name of publisher | Rubber Chemistry and Technology, 96(1): 2023. 1-19 |
| Year of publication | 2023 |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | A 2-thiobenzothiazole/p-phenylenediamine vulcanization intermediate has been characterized by means of ultra-high-performance liquid chromatography–tandem quadrupole time-of-flight mass spectrometry. Pregenerated 2-thiobenzothiazole/p-phenylenediamine intermediate has a clear effect on accelerating the sulfur crosslinking reaction. Therefore, the generation of vulcanization active species can act as a proof that p-phenylenediamine antioxidant could exert an influence on the vulcanization process via a reaction with the accelerator. Based on an analysis of samples from different curing stages, it is speculated that the intermediate is most likely generated in the vulcanization induction period. This research also provides indirect evidence of the effect of zinc oxide on vulcanization. The intermediate can be detected in both solution and vulcanizate. Its formation is likely to be a zinc ion–mediated reversible mechanism involving a radical course. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Vulcanization |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Wang, B. |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | zzwu, A. |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Zhang, Q. |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Zhao, W |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Jia, W. |
| 856 ## - ELECTRONIC LOCATION AND ACCESS | |
| Uniform Resource Identifier | https://doi.org/10.5254/rct.22.78973 |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | Journals |
| Withdrawn status | Lost status | Damaged status | Not for loan | Home library | Current library | Date acquired | Koha item type |
|---|---|---|---|---|---|---|---|
| RRII Library | RRII Library | 04/07/2024 | Journals |