The effect of solution soaking pretreatments on the surface chemistry of crumb rubber (Record no. 74955)

MARC details
000 -LEADER
fixed length control field 02399nam a22001937a 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Badughaish, A
245 ## - TITLE STATEMENT
Title The effect of solution soaking pretreatments on the surface chemistry of crumb rubber
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Journal of Rubber Research, 25(5): 451-464
Year of publication 2022
300 ## - PHYSICAL DESCRIPTION
Other physical details November
520 ## - SUMMARY, ETC.
Summary, etc Crumb rubber (CR) is a widely used waste material in asphalt pavement due to its low cost and high elasticity. A broad range of pretreatment methods has been employed to activate CR surface to improve the compatibility between the asphalt materials and CR. However, this was accompanied by increased costs and reduced high-temperature performance of the rubberised asphalt binder. In this study, the outer surface of aggregated CR particles was activated chemically through a series of solution soaking pretreatments. The chemical reactions were detected through the Fourier-Transform Infrared Spectroscopy (FTIR), the surface morphology was verified by a Scanning Electron Microscope (SEM), and the effect of the treatment was investigated by the Dynamic Shear Rheometer (DSR). The results showed that the chemicals used in this study could activate the CR surface. New functional groups such as the carbonyl group bond (C=O) and carbon–nitrogen bond (C-N) were generated, and changes occurred on the C=C stretch peak at 1635 cm−1 and C=C bend peak at 692 cm−1 as the intensity of the peaks increased and decreased, depending on the effect of the solution used. The nitro group intensity was decreased after all pretreatments due to the chemical reactions between the nitro group and the different solutions. The SEM images showed that the mixed solutions (NaOH and KMnO4) had the most significant effect on surface morphology as the CR surface appeared with a large roughness spread over the whole sample. Furthermore, the rutting resistance of the rubberised asphalt binder improved with the decreased index value of the carbonyl and sulfoxide groups of the CR surface. The treatments used in this study improved the surface activation of the CR and enhanced the compatibility of the CR with the asphalt binder.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Crumb rubber
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Fourier-transform infrared spectroscopy(FTIR)
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Solution soaking
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Surface morphology
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Wang, J
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Xiao, F
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier https://doi.org/10.1007/s42464-022-00185-0
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Date acquired Koha item type
        RRII Library RRII Library 21/02/2023 Journals