Utilization of maleic anhydride modified ground EVA waste in NBR vulcanizates (Record no. 72029)

MARC details
000 -LEADER
fixed length control field 01800nam a2200181Ia 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Soares Bluma G
245 #0 - TITLE STATEMENT
Title Utilization of maleic anhydride modified ground EVA waste in NBR vulcanizates
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Rubber Chemistry and Technology
Year of publication 2005
300 ## - PHYSICAL DESCRIPTION
Number of Pages 16-Jan
520 ## - SUMMARY, ETC.
Summary, etc The influence of poly(ethylene-co-vinyl acetate) (EVA) waste (EVAW) on the rheological and mechanical properties of NBR vulcanizates compounds was studied. The optimum concentration of EVAW, which has presented higher ultimate tensile strength, was found to be 70 phr. In addition, the influence of EVAW modified with maleic anhydride as adhesion promoter was studied. Two distinct routes of modification with maleic anhydride were selected, originating a carboxylated EVA waste (EVAWCOOH) and an anhydride EVA waste (EVAWMA). An improvement of tensile strength and aging resistance was observed with the substitution of EVAW by EVAWCOOH or EVAWMA. A very good resistance to compression set has been achieved with the addition of EVAWCOOH. The improvement of mechanical performance was attributed to a better dispersion of EVAW along NBR matrix, promoted by the enhanced modified-waste polarity, which allowed a good interaction with polar NBR. The presence of anhydride group in functionalized EVAW resulted in the highest values of tensile strength but lower elongation at break and also lower values of tan delta obtained from dynamic testing. These behaviors have been attributed to an increase of crosslink density due to the reaction between zinc oxide and succinic pendant groups of EVAWMA.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term EVA waste
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term NBR vulcanizates
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Gomes Ana C O
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Moreira Viviane X
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Oliveira Marcia G
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Koha item type
      Journals RRII Library RRII Library Rubber chemistry 17/12/2021 Volume 78, Issue 1 Journals