The Effects of isomerization and vulcanisation temperature on the tear strength of natural rubber latex film (Record no. 70663)

MARC details
000 -LEADER
fixed length control field 01928nam a2200265Ia 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Samsuri Azemi
245 #4 - TITLE STATEMENT
Title The Effects of isomerization and vulcanisation temperature on the tear strength of natural rubber latex film
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Journal of Rubber Research
Year of publication 2005
300 ## - PHYSICAL DESCRIPTION
Number of Pages 16-24
520 ## - SUMMARY, ETC.
Summary, etc Natural rubber (NR) is predominantly (100;) cis 1,4 polyisoprene. As a consequence of its regular microstructure, vulcanised NR can undergo strain-crystallisation. In the case of NR latex film, strain-crystallisation promotes knotty tearing, a peculiar feature which is commonly observed in reinforcing black-filled NR vulcanisate but not in NR unfilled (gum) vulcanisate prepared from dry rubber. Knotty tearing enhances the tear strength of NR latex film, where its tearing energy can reach 100 kJm-2. The effects of isomerization, and temperature of vulcanisation on the tear strength of NR latex film were investigated. Isomerisation of NR latex disturbs the regularity of the microstructure and thus inhibits strain-crystallisation. In the absence of strain-crystallisation, NR latex film did not produce knotty tearing. Consequently its tearing energy was relatively low (1.0 kJm-2 - 12 kJm-2) depending on the speed of the test. The tearing energy of NR latex film was also found to decrease as the temperature of vulcanisation was increased which might be attributed to lower concentration of polysulphidic type of crosslinks at high vulcanisation temperature than that produced at low temperature vulcanisation.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Black-filled
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Topical Term Energy
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Topical Term Isomerization
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Topical Term Latex film
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Topical Term MIcrostructure
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Topical Term Natural Rubber
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Topical Term Strain-crystallisation
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Strength
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Topical Term TEar
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Topical Term Tempearature
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Unfilled
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Vulcanisate
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Koha item type
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