Synthesis of graft copolymers from highly deproteinised natural rubber (Record no. 70149)

MARC details
000 -LEADER
fixed length control field 01429nam a2200145Ia 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Fukushima Yuichi
245 #0 - TITLE STATEMENT
Title Synthesis of graft copolymers from highly deproteinised natural rubber
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Journal of Rubber Research
Year of publication 1998
300 ## - PHYSICAL DESCRIPTION
Number of Pages 154-166
520 ## - SUMMARY, ETC.
Summary, etc Highly deproteinised natural rubber(HDPNR) latex was prepared by incubation of commercial high ammonia latex with a proteolytic enzyme in the presence of a surfactant, followed by repeated centrigugation for two times. The nitrogen content of HDPNR was less than 0,.02;, suggesting the nearly complete removal of protein from the rubber. A graft copolymer of natural rubber with styrene was made from HDPNR latex using trtbutyl hydroperoxie/tetraethylenepentamine (TBHPO-TEPA) as an organic redoex initiator.The styrene content, grafting efficiency and molecular weight of grafted polystyrene were significantly increased by deproteinisation. The number of grafting sites for grafting sites for graft copolymer from HDPNR latex was about three times larger than that determined for graft copolymer from untreated natural rubber latex. The difference between the behaviour of HDPNR and untreated natural rubber was due to the removal of protein and of naturally occurring antioxidants present in untreated natural rubber latex.
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Kawahara Seiichi
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Tanaka Yasuyuki
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Koha item type
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