Preparation and properties of chlorinated epoxidised natural rubber latex and its latex-based adhesive (Record no. 65559)

MARC details
000 -LEADER
fixed length control field 01778nam a2200205Ia 4500
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Personal name Thitithammawong A
245 #0 - TITLE STATEMENT
Title Preparation and properties of chlorinated epoxidised natural rubber latex and its latex-based adhesive
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Journal of Rubber Research
Year of publication 2012
300 ## - PHYSICAL DESCRIPTION
Number of Pages 19-34
500 ## - GENERAL NOTE
General note Source Year: 2012
520 ## - SUMMARY, ETC.
Summary, etc Chlorinated epoxidised natural rubber (CENR) was synthesised using epoxidised natural rubber (ENR) in its latex state with an in-situ chloride ion generating substance. The influences of the molar ratios of sodium hypochlorite/sodium chloride (NaOCl/NaCl), pH and the concentration of the NaOCl/NaCl, and reaction time on the level of chlorine contents in the CENR molecules were investigated. FTIR observation showed the presence of a C-Cl band in the rubber structure upon chlorination of the ENR by mixing it with NaOCl and NaCl. The thermogravimetric analysis proved that chlorination provided the CENR with superior thermal stability than that of the ENR. The CENR latex was then formulated and compounded to prepare a latex-based adhesive. It was found that crosslink reactions generated by different vulcanisation systems caused different adhesive strengths in terms of shear strength and cleavage peel strength. Furthermore, the adhesive exhibited higher shear strength than the commercial grade adhesives (i.e. Contact and Dragon) where comparable peel strengths were obtained. However, both properties were relatively lower when compared with Diabond.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Chlorinated epoxidised natural rubber
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Latex based adhesive
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Topical Term Sodium chloride
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Sodium hypochlorite
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Personal name Nakason C
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Personal name Ruttanasupa N
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
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