Kinetics of decomposition of Tert-butyl peroxyisobutyrate during vulcanisation of natural rubber latex (Record no. 61869)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 01219nam a2200169Ia 4500 |
| 100 ## - MAIN ENTRY--AUTHOR NAME | |
| Personal name | Mazam Md Said |
| 245 #0 - TITLE STATEMENT | |
| Title | Kinetics of decomposition of Tert-butyl peroxyisobutyrate during vulcanisation of natural rubber latex |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
| Name of publisher | Journal of Natural Rubber Research |
| Year of publication | 1991 |
| 300 ## - PHYSICAL DESCRIPTION | |
| Number of Pages | 158-171 |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | The development of a modified iodometric method of estimating the concentration of tert-butyl peroxyisobutyrate (tBPIB) in natural rubber (NR) latex is described. The decomposition of tBPIB in NR latex, in the presence or absence of fructose was found to be a first-order reaction with respect to tBPIB concentration. The initial rate of tBPIB decomposition, however, was found to be half order with respect to initial tBPIB concentration. The effect of reaction variables on the rate of tBPIB decomposition is discussed. The activation parameters are calculated from the rate measurements. The significance of the kinetics of decomposition in relation to tBPIB reaction and the kinetics of crosslinking is discussed. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | NR latex |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Tert-butyl peroxyisobutyrate |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Blackley D C |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Pendle T D |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | Journals |
| Withdrawn status | Lost status | Damaged status | Not for loan | Home library | Current library | Date acquired | Serial Enumeration / chronology | Koha item type |
|---|---|---|---|---|---|---|---|---|
| Journals | RRII Library | RRII Library | 17/12/2021 | Volume 6, Issue 3 | Journals |