Epoxidised natural rubber layered silicates nanocomposites (Record no. 58737)

MARC details
000 -LEADER
fixed length control field 02039nam a2200205Ia 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Madhusoodhanan KN
245 #0 - TITLE STATEMENT
Title Epoxidised natural rubber layered silicates nanocomposites
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher Rubber Science
Year of publication 2013
300 ## - PHYSICAL DESCRIPTION
Number of Pages 142-147
520 ## - SUMMARY, ETC.
Summary, etc Polymer/layered silicate nanocomposites exhibit remarkable improvement in mechanical and barrier properties compared to their virgin polymers or microcomposites. Nanoclay being organophilic are more compatible with polar polymers. Epoxidised natural rubber (ENR), a polar form of natural rubber is expected to show high affinity and better performance with layered silicates. Epoxidised natural rubber nanocomposites were prepared by melt compounding of ENR having an epoxy content of 50 mole per cent at ambient temperature. Two grades of organically modified montmorillonite (MMT) having layer distances of 2.1 and 1.85 nm were used in this study. Accelerated sulphur curing system was used for the vulcanizationof the composites. For comparison, commercial clay was included in this study and the filler loading was kept at 10 phr in all mixes. The cure characterestics and mechanical properties were evaluated. The dispersion of the silicate in the matrix was studied by transmission electrone microscopy (TEM). The addition of modified MMT to the ENR reduced its cure time and scorch time. The maximumtorque was higher for these composites.The montmorillonite filled composite showed better mechanical properties when compared to the reference material. The enhancement in properties was believed to be due to the partial exfoliation/intercalation of the layered silicates in ENR. Amog the two types of nanoclays, the one having higher inter-higher distance showed better mechanical properties.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Epoxidised natural rubber
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Exfoliation
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Intercalation
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Layered silicate
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Montmorillonite
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Nanocomposites
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Varghese Siby
942 ## - ADDED ENTRY ELEMENTS (KOHA)
Koha item type Journals
Holdings
Withdrawn status Lost status Damaged status Not for loan Home library Current library Shelving location Date acquired Serial Enumeration / chronology Koha item type
      Journals RRII Library RRII Library Rubber technology 26/07/2013 Volume 26, Issue 1 Journals