Effect of devulcanization on crosslink density and crosslink distribution of carbon black filled natural rubber vulcanizates (Record no. 57783)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02514nam a2200205Ia 4500 |
| 100 ## - MAIN ENTRY--AUTHOR NAME | |
| Personal name | Joseph A M |
| 245 #0 - TITLE STATEMENT | |
| Title | Effect of devulcanization on crosslink density and crosslink distribution of carbon black filled natural rubber vulcanizates |
| 260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
| Name of publisher | Rubber Chemistry and Technology |
| Year of publication | 2016 |
| 300 ## - PHYSICAL DESCRIPTION | |
| Number of Pages | 653-670 |
| 500 ## - GENERAL NOTE | |
| General note | Source Year: 2016 |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | Carbon black filled natural rubber (NR) vulcanizates were devulcanized at ambient temperature in a two roll mill. The effect of cure system, that is, conventional vulcanization (CV), semiefficient vulcanization (semi EV), and efficient vulcanization (EV) systems, used for vulcanization of the original sample, on the efficiency of devulcanization was studied. The efficiency of devulcanization expressed as percentage devulcanization of the samples calculated from residual crosslink density measurements was correlated with the sol fraction of the devulcanized samples based on Horikx analysis. Using chemical probe analysis, we determined (i) the crosslink distribution pattern of the original sample, (ii) the extent to which the different types of crosslinks-that is, polysulfidic, disulfidic, and monosulfidic crosslinks-have been debonded or broken during the shearing process in the two roll mill, and (iii) the pattern of bond formation during revulcanization. Mechanical shearing predominantly breaks the majority crosslink type (polysulfidic crosslinks in CV and semi EV cure systems and disulfidic crosslinks in EV samples). Irrespective of the significant reduction in total crosslink density in all three sets of samples, chain shortening reactions similar to the post-crosslinking chemical reactions at curing temperatures also occur during mechanical shear at ambient conditions, which increased the absolute value of monosulfidic links in CV and semi EV systems. However, in the devulcanized EV system, the absolute value of polysulfidic crosslinks increased, which might be due to the re-crosslinking of the cleaved bonds. All the devulcanized samples were revulcanized, and the mechanical and morphological properties were analyzed. The percentage retention of the vulcanizate properties after revulcanization of the devulcanized samples correlated vry well with efficiency of devulcanization. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Carbon black |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Crosslink density |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Devulcanization |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Alex R |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | George B |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Madhusoodanan K N |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | Journals |
| Withdrawn status | Lost status | Damaged status | Not for loan | Home library | Current library | Shelving location | Date acquired | Serial Enumeration / chronology | Koha item type |
|---|---|---|---|---|---|---|---|---|---|
| Journals | RRII Library | RRII Library | Rubber technology | 01/01/2021 | Volume 89, Issue 4 | Journals |