Carbon-silica dual phase filler, a new generation reinforcing agent for rubber.VIII. Surface characterisation by IGC (Record no. 55201)

MARC details
000 -LEADER
fixed length control field 01943nam a2200217Ia 4500
100 ## - MAIN ENTRY--AUTHOR NAME
Personal name Wang M J
245 #0 - TITLE STATEMENT
Title Carbon-silica dual phase filler, a new generation reinforcing agent for rubber.VIII. Surface characterisation by IGC
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT)
Name of publisher 156th ACS Rubber Division Meeting 1999. Conference preprints, Orlando 21st to 23rd Sep 1999.
500 ## - GENERAL NOTE
General note Source Year: 2000
520 ## - SUMMARY, ETC.
Summary, etc The surface characteristics of carbon-silica dual phase filler (CSDPF) are investigated by means of inverse gas chromatography (IGC) at infinite dilution. It is found that due to its unique surface microstructure, the dispersive component of the surface energy of CSDPF is considerably higher than those of carbon black and silica. Among CSDPFs, the surface energies increase with increasing surface area. The adsorption energies of a series of hydrocarbon probes and polar compounds are also measured with IGC. Relative to conventional fillers, the higher adsorption energies of hydrocarbon probes and polar compounds on dual phase fillers as well as their higher surface energy suggest a stronger interaction with hydrocarbon polymers. This is consistent with observations on bound rubber measurement. The overall polarity of CSDPF and the specific or polar component of the surface energy of MPF are estimated from specific free energies of adsorption of polar compounds. The polarity of this new filler, while being similar to that of its carbon black counterpart, is substantially lower than the polarity of precipitated silica. This will result in a high compatibility of this dual phase filler with hydrocarbon rubber, leading to lower filler-filler interaction and better microdispersion.
650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM
Topical Term Carbon-silica
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Topical Term Filler
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Topical Term IGC
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Topical Term Reinforcing agent
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Personal name Mahmud K
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Personal name Murphy L J
700 ## - ADDED ENTRY--PERSONAL NAME
Personal name Tu H
856 ## - ELECTRONIC LOCATION AND ACCESS
Uniform Resource Identifier RAPRA
942 ## - ADDED ENTRY ELEMENTS (KOHA)
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