Studies in molecular weight determination of rubber seed oil alkyds (Record no. 47350)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02050nam a2200181Ia 4500 |
| 100 ## - MAIN ENTRY--AUTHOR NAME | |
| Personal name | Okieimen F E |
| 245 #0 - TITLE STATEMENT | |
| Title | Studies in molecular weight determination of rubber seed oil alkyds |
| 520 ## - SUMMARY, ETC. | |
| Summary, etc | Molecular weights of six samples of rubber seed oil alkyds having oil content of 20;(I), 30;(II), 35;(III), 40;(IV), 50;(V), and 60;(VI) prepared with phthalic anhydride, glycerol and rubber seed oil were determined (Rast methos) and calculated (endgroup analysis). Properties of the rubber seed oil were specific gravity 0.926, colour 0.5R 10Y, free fatty acid 11.29, peroxide value 0.40, saponification value 192.93, iodine value 155.56 and unsaponifiable matter (;)0.84. Average molecular weights determined, ranged from 441.11 for sample III to 1323.33 for sample V and those calculated were found to be larger than the values determined. Rast method seems to be a more reasonable method of average molecular weight determination for routine analysis. The differences observed were attributed to the assumption that only interesterification reactions occur during alkyd preparation in calculating average molecular weights. Fractionation of the alkyds showed that rubber seed oilalkyds consist of fractions of varying molecularweights. Study of molecular weight distribution showed that species of low average molecular weight constitute greater proportion of the alkyds. Average molecular weihts of the final alkyds to air-dry was found to be dependent on solid content, viscocity of alkyd solution and level of unsaturation in the final alkyd. Thus alkyds containing 40;rubber seed oil and above were found to be air-drying while those containing lower oil content are considered suitable in formulating baked finishes or can be combined with other film-forming resins. |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Alkyd resins |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Average molecular weight |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Polymerization |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Rubber seed oil |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| Topical Term | Viscosity |
| 700 ## - ADDED ENTRY--PERSONAL NAME | |
| Personal name | Aigbodion A I |
| 942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
| Koha item type | Bibliography RLSE |
| 650 ## - SUBJECT ADDED ENTRY--TOPICAL TERM | |
| -- | rying time |
| Withdrawn status | Lost status | Damaged status | Not for loan | Home library | Current library | Date acquired | Koha item type |
|---|---|---|---|---|---|---|---|
| Bibliography | RRII Library | RRII Library | 31/12/2021 | Bibliography RLSE |