Role of particle cavitation in rubber-toughened epoxies : 1. Microvoid toughening
Bagheri R
Role of particle cavitation in rubber-toughened epoxies : 1. Microvoid toughening - Polymer 1996 - 4529-4538
The significance of particle cavitation in rubber-toughened polymers remains controversial. While some researchers believe void formation promotes shear yielding in the polymer matrix, others consider it as a secondary energy consuming process. The research described here was undertaken to further elucidate the role of particle cavitation in toughening through comparative examination of epoxies modified by conventional rubber modifiers and hollow plastic particles. The results of this study illustrate that rubber particles with different cavitation resistance and pre-existing microvoids toughen the present epoxy matrix in the same manner. The cavitation resistance of the rubbery phase does not directly contribute to toughness, but instead simply allows the matrix to deform by shear. An additional machanism of microcracking was observed when 40mm hollow plastic particles were employed. Despite the similar behaviour in fracture toughness testing, rubber particles and microvoids differ considerably in how they affect the compressive yield strength of the blend. The results of this study suggest the possible importance of inter-particle distance in toughening of epoxies.
Cavitation
Hollow plastic particle
Rubber-toughened epoxies
Role of particle cavitation in rubber-toughened epoxies : 1. Microvoid toughening - Polymer 1996 - 4529-4538
The significance of particle cavitation in rubber-toughened polymers remains controversial. While some researchers believe void formation promotes shear yielding in the polymer matrix, others consider it as a secondary energy consuming process. The research described here was undertaken to further elucidate the role of particle cavitation in toughening through comparative examination of epoxies modified by conventional rubber modifiers and hollow plastic particles. The results of this study illustrate that rubber particles with different cavitation resistance and pre-existing microvoids toughen the present epoxy matrix in the same manner. The cavitation resistance of the rubbery phase does not directly contribute to toughness, but instead simply allows the matrix to deform by shear. An additional machanism of microcracking was observed when 40mm hollow plastic particles were employed. Despite the similar behaviour in fracture toughness testing, rubber particles and microvoids differ considerably in how they affect the compressive yield strength of the blend. The results of this study suggest the possible importance of inter-particle distance in toughening of epoxies.
Cavitation
Hollow plastic particle
Rubber-toughened epoxies